Chlorido(ethyldiphenylphosphine-κP)(1-pyrrolidinecarbodithioato-κ2 S,S′)nickel(II)
نویسندگان
چکیده
In the crystal structure of the title complex, [Ni(C(5)H(8)NS(2))Cl(C(14)H(15)P)], the Ni atom is coordinated by an S,S'-chelating dithio-carbamate, a chloride and a diphenyl-ethyl-phosphine ligand in a distorted square-planar arrangement.
منابع مشابه
(6-Hydroxy-2-{[2-(N-methylcarbamothiolyl)hydrazin-1-ylidene-κ2 N 1,S]methyl}phenolato-κO 1)(triphenylphosphane-κP)nickel(II) chloride
The deprotonated Schiff base ligand in the title salt, [Ni(C(9)H(10)N(3)O(2)S)(C(18)H(15)P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated nickel(II) atom, which exists in a distorted square-planar geometry. The hy-droxy group forms an intra-molecular O-H⋯O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bond...
متن کامل{2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2 N 1,S)methyl]-6-hydroxyphenolato-κO 1}(triphenylphosphine-κP)nickel(II) chloride
The deprotonated Schiff base ligand in the title compound, [Ni(C(8)H(8)N(3)O(2)S)(C(18)H(15)P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hy-droxy group forms an intra-molecular O-H⋯O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds gen...
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In the title compound, [Ni(C(6)H(9)N(4)S(2))Cl], the Ni atom is in a slightly distorted square-planar environment coordinated by a Cl atom and a deprotonated thio-semicarbazone ligand via its thia-zoline N, azomethine N and thiol-ate S atoms. Short inter-molecular N-H⋯Cl and C-H⋯S contacts are present in the crystal structure.
متن کاملDi-μ-chlorido-bis{chlorido[2-(2-furylmethyliminomethyl)pyridine-κ2 N,N′]nickel(II)}
The title dinuclear nickel(II) complex, [Ni(2)Cl(4)(C(11)H(10)N(2)O)(2)], lies on a centre of symmetry located at the centroid of the four-membered ring formed by the two Ni atoms and the bridging chloride ions. The Ni(II) atom is five-coordinated in a square-pyramidal geometry by the imine and pyridine N atoms of the Schiff base ligand, and by one terminal and two bridging Cl atoms. The Ni⋯Ni ...
متن کاملcatena-Poly[[(triphenylphosphane-κP)silver(I)]-μ-4,4′-bipyridine-κ2 N:N′-[(triphenylphosphane-κP)silver(I)]-di-μ-chlorido]
In the title coordination polymer, [Ag2Cl2(C10H8N2)(C18H15P)2] n , the Ag(I) cation is coordinated by a 4,4'-bi-pyridine N atom, a tri-phenyl-phosphane P atom and two Cl(-) anions in a distorted tetra-hedral geometry. The 4,4-bi-pyridine and Cl(-) anions bridge the Ag(I) cations, forming polymeric chains running along [21-1]. In the crystal, weak C-H⋯Cl inter-actions link the polymeric chains i...
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